Q2DSTD NMR deciphers epitope-mapping variability for peptide recognition of integrin αvβ6† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c5ob01237f Click here for additional data file.
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چکیده
[180--90] unit at the head of the sequence provides the adjustable element to measure T 1 of 1 H attached to 13 C. The inter-sequence relaxation delay was set to 5 s and values were 0.2, 0.3, 0.4, 0.5, 0.6, 0.7, 0.8 and 1.0 s to provide intensities for each 1 H resonance correlated to its 13 C in the modified HSQC and example intensity data are shown below for four 1 H-13 C correlations in FMDV2: All phases are 'x' unless otherwise stated 1 = x,-x (incremented for second dimension) GARP 13 C decoupling was used during acquisition using Garp. A comb of 'n' saturation pulses are applied over the required saturation period at the desired frequency offset to provide saturation transfer (on) or not (off).
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General ............................................................................................................................................S1 General Procedure A: Preparation of 3’-Phosphorylated Nucleosides .................................S1 Preparation of 3’-acetylated Nucleosides...................................................................................S8 NMR Studies .........
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